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One mole of a solute A  is dissolved in a given volume of a solvent. The association of the solute take place as follows  n A   An. If a is the degree of association of A, the Van’t Hoff factor i  is expressed as  

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By Expert Faculty of Sri Chaitanya
a
i=1−α
b
i=1+αn
c
i=1−α+αn
d
i=1

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detailed solution

Correct option is C

nA⇌ Anat Initial mole  =1 ,     ni=1At equilibrium state. 1−α          αn,  ⇒ neq=1−α+αn ( \ i = Van’t Hoff factor)  ∴i=neqni   =1−α+αn1             ( \ i = Van’t Hoff factor)  i=1−α+αn


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