O-O single bond enthalpy is 'X' O=O double bond enthalpy is 'Y' correct relation is
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a
2X > Y
b
2X < Y
c
2X = Y
d
2Y = X
answer is B.
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Detailed Solution
sigma bond is very weak due to the repulsions between the adjacent Oxygen atoms 'X' has very low magnitudeA double bond contains one sigma (strong) and a Pi-bond(weak)So Sum of enthalpies of two sigma bonds > Enthalpy of a Double bondBut in the case of OxygenSum of enthalpies of two sigma bonds (2X)< Enthalpy of a Double bond(Y) 2X < Y