Q.
The order of stability of the carbanions :(CH3)3C- (I) ; (CH3)2CH (II) ; CH3CH2 (III) and C6H5CH2 (IV)
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a
I > II > III > IV
b
IV > III > II > I
c
IV > I > II > III
d
I > II > IV > III
answer is B.
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Detailed Solution
Stability Order: Benzyle Carbanion > Alkyl carbonionReason: Due to resonance benzyle carbonion is more stable. As the number of +IE groups [alkyl groups] increases, electron donation towards the carbanion carbon increases, and hence electron density [weight] on the carbanion carbon increases, therefore stability of carbanion carbon increases Hint: As electron density increases, weigth on carbon increases, strain on carbon increases, stability decreases.→ Based on the above rules the stability order of given carbanions.
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