An organic compound "A" on treatment with benzene sulphonyl chloride gives compound B. B is soluble in dil. NaOH solution. Compound A is :
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a
C6H5–N(CH3 )2
b
C6H5–NHCH2CH3
c
C6H5–CH2 NHCH3
d
C6 H5 –CH(CH3)–NH2
answer is D.
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Detailed Solution
In simple words the compound must be primary amine since it reacts with Hiensberg reagent as well as base added and forms a soluble salt, secondary amine only react with Hiensberg reagent not with base, and tertiary amines react with with none.