Q.
Out of the following pairs of electrons, identify the pairs of electrons present in degenerate orbitals.
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a
(i) n=3,l=2,ml=-2,ms=-12 (ii) n=3,l=2,ml=-1,ms=-12
b
(i) n=3,l=1,ml=1,ms=+12 (ii) n=3,l=2,ml=1,ms=+12
c
(i) n=4,l=1,ml=1,ms=+12 (ii) n=3,l=2,ml=1,ms=+12
d
(i) n=3,l=2,ml=+2,ms=-12 (ii) n=3,l=2,ml=+2,ms=+12
answer is A.
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Detailed Solution
Degenerate orbitals means the orbitals of the same subshell of the same main shell, i.e. their n and l values should be same for both the given sets:(a) (i) 3dxy (ii) 3dyz(b) (i) 3 px (ii) 3dxyc) (i) 4 s (ii) 3dxy(d) (i) 3dx2-y2 (ii) 3dx2-y2Thus, 3dxy and 3dyz; 3dx2-y2 and 3dx2-y2 represent pair of degenerate orbitals.
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