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Q.

The oxidation number of nitrogen in NCl3 is

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a

+3

b

-3

c

zero

d

answer is B.

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Detailed Solution

'N' and 'Cl' have same value of EN on pauling scale (EN=3) Nitrogen is smaller than chlorine its oxidation state in NCl3 must be negativeNCl3x + 3(+1) = 0x = -3EvidenceNCl3 + 3H2O → NH3 + 3HOClThe product clearly indicate that the -ve pole nitrogen goes with positive pole of water (H+)
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