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Q.

Oxidising power of chlorine in aqueous solution can be determined by the parameters indicated below: 12Cl2(g)→12ΔdissHoCl(g)→ΔegHoCl−(g)→ΔhydHoCl−(aq)The energy involved in the conversion of 12Cl2(g) to Cl−1(aq)(using the data, ΔdissHCl− =+240 kJ mol−1, ΔegHCl- =−349 kJ mol−1, ΔhydHCl− =−381 kJ mol−1) will be:

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a

+152 kJ mol−1

b

−610 kJ mol−1

c

−850 kJ mol−1

d

+120 kJ mol−1

answer is B.

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Detailed Solution

For the process, 12Cl2(g)→Cl−(aq); ΔH=?12Cl2(g)→Cl(g),                ΔdissHClΦ=240 kJ mol−1Cl(g)+e−→Cl−(g);          ΔegHClΦ=−349 kJ mol−1Cl−(g)+aq.→Cl−(aq);    ΔhydHClΦ=−381 kJ mol−1¯ΔH=ΔdissHCl2Φ2+ΔegHClΦ+ΔhydHCl−Φ=2402+(−349)+(−381)=−610 kJ mol−1
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