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Q.

Oxidizing power of chlorine in aqueous solution can be determined by the parameters indicated below.12Cl2(g)⟶12ΔdissHΘCl(g)⟶ΔHEgΘCl−(g)⟶ΔhydHΘCl−(aq)The energy involved in the conversion of 12Cl2(g) to Cl-(aq) will be(using the data, ΔdissHCl2Θ=240kJmol−1=240kJmol−1ΔEgHClΘ=−349kJmol−1ΔhydHClΘ=−381kJmol−1

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a

+152 kJ mol-1

b

-610 kJ mol-1

c

-850 kJ mol-1

d

+120 kJ mol-1

answer is B.

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Detailed Solution

12Cl2(g)→Cl−(aq)ΔH=12ΔHdissCl2+ΔHEACl+ΔHhydCl− =2402−349−381=−610kJmol−1
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