Q.
P, Z, C and J are the elements belonging to 17th group of Modern periodic table. The correct trend of Bond dissociation enthalpy of these elements is P2 > Z2 > C2 > J2. The element ‘C’ in the sequence is
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a
F
b
Br
c
I
d
Cl
answer is A.
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Detailed Solution
Atomic radius….FCl>Br>I;EN ….F>Cl>Br>I;Electron gain enthalpy ….I
Cl>Br>I>Cl->F->Br->I-B.D.E….Cl2>Br2>F2>I2; Due to small size and repulsions between lone pairs on adjacent Fluorine atoms ;IP …..I-Cl2>Br2>I2;Hydration enthalpy…F->Cl->Br->I-;MP and BP ….F2
Cl>Br>I>Cl->F->Br->I-B.D.E….Cl2>Br2>F2>I2; Due to small size and repulsions between lone pairs on adjacent Fluorine atoms ;IP …..I-
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