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Q.

The pair of compounds in which both the compounds give positive test with Tollens’ reagent is:

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a

glucose and sucrose

b

fructose and sucrose

c

acetophenone and hexanal

d

glucose and fructose

answer is D.

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Detailed Solution

Monosaccharide are reducing in nature. Acetophenone is a ketone and do not give Tollens test, Fructose is also a ketone but due to alpha hydroxy group , it undergoes re-arrangement. Hence option (4) is correct.
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The pair of compounds in which both the compounds give positive test with Tollens’ reagent is: