The partial pressure of CH3OH(g), CO(g) and H2O(g) in equilibrium mixture for the reaction CO(g) + 2H2(g) ⇌ CH3OH(g) are 2.0, 1.0, and 0.1 atm respectively at 4270C. The value of KP for decomposition of CH3OH to CO and H2 is

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102 atm

2 × 102 atm-1

50 atm2

5 × 10-3 atm2

answer is D.

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Detailed Solution

KP = PCH3OHPH22 × PCO = 21 × 0.12 = 200KP for reverse reaction will beKP1 = 1KP = 1200 = 5 × 10-3 atm2

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