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Q.

On passing Cl2 water in a mixture of KBr and KI solution in contact with CCl4 continuously with occasional shaking, we observe

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a

Orange CCl4 layer changing to violet

b

Persisting violet CCl4 layer

c

Persisting brown layer

d

Violet layer changing into brown and finally colourless

answer is D.

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Detailed Solution

Cl2+2I⊖⟶2Cl-+I2⊖Cl2+2Br⊖⟶Br2+2Cl⊖Oxidising agent: Cl2>Br2>I2Hence, CI2 oxidises I⊝ first to I, which gives violet colour in CCl4,then Br2⊝→Br2,which gives brown colour in CCl4, finally 12 is oxidised to IO⊝. Hence, the CCl4 layer turns colourless.
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