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Q.

p-chloro aniline and anilinium hydrochloride can be distinguished by

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a

Sandmeyer's reaction

b

AgNO3

c

Liebermann's nitroso reaction

d

carbylamine test

answer is B.

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Detailed Solution

AgNO3 gives white ppt. of AgCl with anilinium hydrochloride because of the presence of free chlorine in it but p-chloroaniline gives no reaction with it. Hence, AgNO3 can be used to distinguish them.
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p-chloro aniline and anilinium hydrochloride can be distinguished by