p-chloro aniline and anilinium hydrochloride can be distinguished by
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a
Sandmeyer's reaction
b
AgNO3
c
Liebermann's nitroso reaction
d
carbylamine test
answer is B.
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Detailed Solution
AgNO3 gives white ppt. of AgCl with anilinium hydrochloride because of the presence of free chlorine in it but p-chloroaniline gives no reaction with it. Hence, AgNO3 can be used to distinguish them.