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Q.

PCI5 is formed when:

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a

white phosphorus reacts with limited dry chlorine

b

white phosphorous reacts with excess of dry chlorine

c

white phosphorus reacts with excess of SO2Cl2

d

white phosphorus reacts with excess of SO2Cl2

answer is B.

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Detailed Solution

(1) P4+6Cl2⟶4PCl3(2) P4+10Cl2⟶4PCl5 (Excess)(3) P4+8SOCl2⟶4PCl3+4SO2+2S2Cl2(4) P4+10SO2Cl2⟶4PCl5+10SO2
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PCI5 is formed when: