PdFCIBrI2−has n number of geometrical isomers. Then , the spin-only magnetic moment and crystal field stabilization energy [CFSE] of FeCN6n−6 respectively, are : (Note : ignore the pairing energy )
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a
0 BM and −2.4 Δ0
b
2.84 BM and −1.6 Δ0
c
1.73 BM and −2.0 Δ0
d
5.92 BM and 0
answer is C.
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Detailed Solution
The given complex is [MABCD] type complex ⇒ No. of G.I n=3The cyanide complex is FeCN63−Fe3+→d5 Config +SFLCFT config:−t2g221 eg00no of unpaired e−=1 ⇒μ11+2=3 =173BMCSFE=-0.4Δ0×nt2g+0.6Δ0×neg=-0.4Δ0×5+0.6Δ0×0=-2.0Δ0