First slide
Salt hydrolysis :
Question

The pH of aqueous solution of NH4CN (Ka of HCN is 9.2 × 10–10 & Kb of NH4OH is 1.8 × 10–5)

Moderate
Solution

PH of a salt of weak acid and weak base is given as

\large {P^H} = \frac{1}{2}\left[ {{P^{{K_w}}} + {P^{{K_a}}} - {P^{{K_b}}}} \right]
\large \Rightarrow {P^H} = \frac{1}{2}\left [ 14+8.05-4.74 \right ]= 8.655

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