Q.
pH of a buffer solution decreases by 0.02 units when 0.12 g of acetic acid is added to 250 mL of a buffer solution of acetic acid and potassium acetate at 27oC. The buffer capacity of the solution is
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a
0.1
b
10
c
1
d
0.4
answer is D.
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Detailed Solution
Buffer capacity, ∅ = No.of molesof acid added/litChange in PHNo.of moles of acetic acid/lit = 0.1260×1000250 =8×10-3 ∅=8×10-32×10-2=0.4
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