Phosphorus pentachloride dissociates as follows, in a closed reaction vessel,PCl5(g) ⇌PCl3(g) + Cl2(g)If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of PCl5 is x, the partial pressure of PCl3 will be
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a
x1-xP
b
xx+1P
c
2x1-xP
d
xx-1P
answer is B.
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Detailed Solution
PCl5(g) ⇌PCl3(g) + Cl2(g)1 0 01 - x x x∴ KC = x21-x Peq1 + x Also P'PCl3 = Peq.. x1 + x