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Q.

Phosphorus pentachloride dissociates as follows, in a closed reaction vessel,PCl5(g)  ⇌PCl3(g)  +  Cl2(g)If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of PCl5 is x, the partial pressure of PCl3 will be

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a

x1-xP

b

xx+1P

c

2x1-xP

d

xx-1P

answer is B.

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Detailed Solution

PCl5(g)  ⇌PCl3(g)  +  Cl2(g)1                   0                  01 - x              x                  x∴       KC = x21-x  Peq1 + x Also    P'PCl3 = Peq.. x1 + x
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