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Pick out from the following complex compounds, a poor electrolytic conductor in solution?

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By Expert Faculty of Sri Chaitanya
a
K2PtCl6
b
CoNH33NO23
c
K4FeCN6
d
CoNH34SO4

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detailed solution

Correct option is B

CoNH33NO23 There is no ions out of the coordination sphere thus it is poor conductor in electrolytic solution K2PtCl6=3 ionsCoNH33NO23= out of the coordination sphere no ions (non ionisable)K4FeCN6=5 ionsCoNH34.SO4=2 ionsMore ions ∝ more conductivity


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According to werner primary valency of  central atom in  Pt(en)H2OCl3Cl Complex is 

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