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Q.

The pKa of a weak acid (HA) is 4.5. The pOH of an aqueous buffered solution of HA in which 50% of the acid is ionized is

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a

4.5

b

2.5

c

9.5

d

7.0

answer is C.

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Detailed Solution

For buffer solution :pH = pKa + log  SaltAcid = 4.5 + log  SaltAcid As HA is 50% ionized so  Salt = Acid pH = 4.5 pH + pOH = 14 ∴     pOH = 14 - 4.5 = 9.5
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