Presence of primary alcohol group in glucose is indicated by its reaction with – ‘X’. Presence of aldehyde group in glucose is indicated by its reaction with ‘Y’. ‘X’ & ‘Y’ respectively are
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a
Conc. HNO3; Br2/H2O
b
Dil. HNO3; AgNH32+
c
Dil. HNO3; HCN
d
Conc. HNO3; NaHSO3
answer is A.
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Detailed Solution
Conc. HNO3… strong oxidant – not only oxidizes -CHO gp to -COOH but also oxidizes −CH2OH− group also to -COOH group;Br2/H2O , Tollen’s, Fehling’s, Benedict’s .. mild oxidants.. oxidizes -CHO group only to -COOH group
Presence of primary alcohol group in glucose is indicated by its reaction with – ‘X’. Presence of aldehyde group in glucose is indicated by its reaction with ‘Y’. ‘X’ & ‘Y’ respectively are