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Q.

Primary alcohol can easily be prepared from primary alkyl halide via SN2 reaction with aqueous NaOH. However, similar method does not work for the preparation of tertiary alcohol (tertiary butanol) from tertiary butyl bromide except?

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a

CH33CBr+CH3COOAgaq→→H3O+

b

CH33CBr+KOH→→C2H5OH→Heatdil. H2SO4

c

CH33CBr→C2H52OMg→ii H3O+i O2

d

CH33CBr→KOH/Ethanol→ii H2O2/NaOHi B2H6

answer is D.

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Detailed Solution

CH33CBr→KOH/EthanolCH32C=CH2→2H2O2/NaOH1B2H6CH32CHCH2OHA primary alocohol is obtained.
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