Q.

The process is called N - acylation of aniline. The correct reactivity order for this reaction when ‘X’ is.

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a

(CH3CO)2O>CH3COCl>CH3COOC2H5

b

CH3COOC2H5>CH3COCl>(CH3CO)2O

c

(CH3CO)2O>CH3COOC2H5>CH3COCl

d

CH3COCl>(CH3CO)2O>CH3COOC2H5

answer is D.

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Detailed Solution

C6H5-NH-H+Z-CO||-CH3→pyridineC6H5NH-CO||-CH3+HZ-Z is the leaving groupLeaving group ability of -Cl > -OCOCH3 > -OC2H5Leaving group ability ∝1basic strengthAcidic strength of HCl > CH3COOH > C2H5OHBasic strength of Cl- < CH3COO- < C2H5O- .
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