Q.

The products (A) and (B) are, respectively:

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a

KI,I2

b

I2 ,KIO3

c

KIO3 ,KIO4

d

I2 ,I2

answer is B.

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Detailed Solution

Acidic medium: Iodine is liberated from potassium iodide10I- + 2MnO4- + 16H+ → 2Mn2+ + 8H2O + 5I2Alkaline medium: Iodide is oxidized to iodate2MnO4- + H2O + I-→ 2MnO2 + 2OH- + IO3-
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