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Q.

Propene CH3−CH=CH2 can be converted to 1-propanol by oxidation. Which set of reagents among the following is ideal to effect the conversion?

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a

Alkaline KMnO4

b

B2H6 and alkaline H2O2

c

O3Zn dust

d

OsO4CH4,Cl2

answer is B.

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Detailed Solution

In the Conversion of propene to 1-propanol by oxidation the reagent used is B2H6 and alkaline H2O2 ,this reaction is  also called hydroboration-oxidation reaction.  During hydroboration-oxidation of alkenes addition of water to the double bond takes place in anti-Markownikoff fashion. Since negative part of water attached to higher number of hydrogen of carbon atom of unsymmetrical alkenes.
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