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Q.

Propyne→∆Na X +12H2                  X →∆CH3IY  Now, which of the following reagents can be used to distinguish Y from propyne?

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a

NH4OH + AgNO3 (or) cold alk KMnO4

b

NH4OH + Cu2Cl2 (or) Br2/ CCl4

c

Cold alk. KMnO4 (or) Br2 / CCl4

d

NH4OH + AgNO3 (or) NH4OH + Cu2Cl2

answer is D.

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Detailed Solution

Propyne is a terminal alkyne and exhibits acidic character,hence they gives +ve test with NH4OH+AgNO3 and NH4OH+Cu2Cl2Where as Y[but-2-yne] is a internal alkyne,it does not contain acidic hydrogen,hence it does not give +ve test with the above two reagents.
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Propyne→∆Na X +12H2                  X →∆CH3IY  Now, which of the following reagents can be used to distinguish Y from propyne?