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Q.

Pure  C=O   bond length  is X pm and pure C≡O bond length is Y pm.Carbon - Oxygen bond length in CO2 is

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a

Greater than Y pm but lesser than X pm

b

Lesser than Y pm but greater than X pm

c

Lesser than X pm but equal to Y pm

d

Greater than Y pm but equal to X pm

answer is A.

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Detailed Solution

Pure C=O  bond length is 121 pm and pure C≡O bond length is 110 pm.  Carbon - Oxygen bond length  in CO2 is 115 pm. This is due to resonance in CO2.
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