In pure liquid of HCOOH, concentration of HCOO- = 10-3 M at 270C. What is the self-ionisation constant K = HCOOH2+ HCOO-
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a
10-3
b
103
c
106
d
10-6
answer is D.
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Detailed Solution
In pure liquid the following equilibrium exists.HCOOH+HCOOH⇌HCOOH2++HCOO-K=HCOOH2+HCOO-HCOOH2 For pure liquid HCOOH=1 MK = HCOOH2+ HCOO- = 10-3 × 10-3 = 10-6