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Q.

Aqueous solution of AgNO3 is electrolysed using Pt electrodes. Products obtained at anode and cathode respectively

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a

Ag, O2

b

Ag, NO2

c

O2, Ag

d

H2, O2

answer is C.

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Detailed Solution

At cathodeEAg+/Ago >  EH+/12H2,Pto∴ Ag++e−→Ag↓×4At anodeSRP  of  NO3−/NO2,   NO3−/NO  are high EO2/H2Oo <  ENO3−/NOxo(or)  SOP of  EH2O/O2o >  ENOx/NO3-o2H2O → 4H++4e−+O2
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