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Question

$R - B r \overset{M g / e t h e r}{\to} A \overset{D_{2} O}{\to} C H_{3} C H_{2} D$ , R-Br by Wurtz reaction gives rise to which of the following product(s)

Solution

$C_{2} H_{5} - B r \overset{M g / e t h e r}{\to} C_{2} H_{5} M g B r \overset{D_{2} O}{\to} C H_{3} C H_{2} D$ , So, R-Br is ethyl bromide on reaction with sodium metal it forms n-Butane as major product as follows , $2 C_{2} H_{5} - B r \overset{N a / e t h e r}{\to} C_{2} H_{5} - C_{2} H_{5}$

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