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a
b
(CH3)2CHOH
c
(CH3)2CHCH2OH
d
answer is B.
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Detailed Solution
H-CH|=O+RMgX→H-CR|H|-OMgX→H2OH-CR|H|-OH(1o alcohol)+Mg(X)OHSo what so ever is the size and length of -R group in RMgX, if it is treated with HCHO followed by hydrolysis the ultimate product is RCH2OH(1°)1, 3, 4 are 1° alcohols ;2 is 2° alcohol which cannot be obtained using HCHO and RMgX.