Q.
The rate constant (k) of a reaction is measured at different temperatures (T), and the data are plotted in the given figure. The activation energy of the reaction in kJ mol-1 is : (R is gas constant)
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a
1/R
b
2/R
c
2R
d
R
answer is C.
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Detailed Solution
lnK=lnA−EaRT→103T=0 i.e T→∞i.e lnK=lnAat origin lnK=10=ln A→at 103T=5 ⇒ T=200K lnK=0lnA=EaRT10=EaR200Ea = 2000 R J = 2R kJ/mole
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