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Q.

The rate equation for the reaction  2A+B→C  is found to be : rate = K[A][B]. The correct statement in relation to this reaction is

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a

unit of k must be sec-1

b

value of k is independent of the initial concentrations of A and B

c

rate of formation of C is twice the rate of disappearance of A

d

t12  is a constant

answer is B.

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Detailed Solution

(1) Rate = K[A][B]     (2) Rate constant (k) depends only on temperature and catalyst.(3)  2A + B → C   Rate formation of 'C' is half the rate of disappearance of 'A'(4)  for 2nd order             only option (2) is correct.
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