Ratio of moles of Fe (II) oxidised by equal volumes of equimolar KMnO4 and K2Cr2O7 solutions in acidic medium will be:
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a
5:3
b
1:1
c
1:2
d
5:6
answer is D.
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Detailed Solution
Fe2++MnO4−⟶Fe3++Mn2+nf =7 nf =5Moles of Fe2+ x 1 by KMnO4=moles of MnO4−×5 ...(1)Fe2++Cr2O72−⟶Fe3++Cr3+nf =7 nf =6Moles of Fe2+ x 1 by K2Cr2O7=moles of MnO4−×6 ...(2)(1)+(2)n1n2=56