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Q.

Ratio of moles of Fe (II) oxidised by equal volumes of equimolar KMnO4 and K2Cr2O7 solutions in acidic medium will be:

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a

5:3

b

1:1

c

1:2

d

5:6

answer is D.

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Detailed Solution

Fe2++MnO4−⟶Fe3++Mn2+nf =7 nf =5Moles of Fe2+ x 1 by KMnO4=moles of MnO4−×5 ...(1)Fe2++Cr2O72−⟶Fe3++Cr3+nf =7 nf =6Moles of Fe2+ x 1 by K2Cr2O7=moles of MnO4−×6 ...(2)(1)+(2)n1n2=56
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