Q.

Reactant A gives product B or CThe possible reagents are:(I) 2Na/liq.NH3 (II) H2/Pd/CaCO3 (quinoline)  (III) 2H2/Pd/CThe correct statement with respect to the above conversion is/are:

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a

B is obtained on treatment with reagent (I)

b

C and B are obtained on treatment with reagent (II)

c

C is obtained on treatment with reagent (I)

d

C is obtained on treatment with reagent (II)

answer is C.

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Detailed Solution

Reagent (I) gives trans product. Reagents (II) and (III) give cis-product. The reagent I is called as Birch reagent and the intermediate is di anion and it is stable in trans form.
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Reactant A gives product B or CThe possible reagents are:(I) 2Na/liq.NH3 (II) H2/Pd/CaCO3 (quinoline)  (III) 2H2/Pd/CThe correct statement with respect to the above conversion is/are: