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Q.

In a reactionAB(g)⇌A(g)+B(g) , the value of KP  is numerically equal to one third of the total equilibrium pressure P. The percent dissociation of AB is

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a

25

b

30.5

c

40

d

50

answer is D.

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Detailed Solution

AB(g)⇌A(g)+B(g)1−α                      α              α PA=PB=α1+αP;  PAB=1−α1+αP KP=PA×PBPAB⇒P3=(α1+αP)2(1−α1+αP)=α2P1−α2⇒α=12
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