Q.

For the reaction H2(g)+CO2(g)⇌CO(g)+H2O(g)  If the initial concenffation of H2=CO2=1M and x  moles,/litre of hydrogen is consumed at equilibrium, the correct expression of K p is

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a

x2(1−x)2

b

(1+x)2(1−x)2

c

x2(2+x)2

d

x21−x2

answer is B.

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Detailed Solution

H2(g)+CO2(g)⇌CO(g)+H2O(g) t=0;    1M       1M            0            0 teq.;   (1-x)   (1-x)        (x)          (x) Δng=0 ⇒ kp=kc=x2(1-x)2
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For the reaction H2(g)+CO2(g)⇌CO(g)+H2O(g)  If the initial concenffation of H2=CO2=1M and x  moles,/litre of hydrogen is consumed at equilibrium, the correct expression of K p is