Q.

For the reaction (I) and (II)  (I)A(g)⇌B(g)+C(g);(II) X(g)⇌2Y(g)  Given, KPI:KPII=9:1 If the degree of dissociation of A(g) and X(g) be same then the total pressure at equilibrium (I) and (II) are in the ratio :

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a

3 : 1

b

36 : 1

c

1 : 1

d

1 : 36

answer is B.

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Detailed Solution

A(g)⇌B(g)+C(g) t=0 a mole  teq.(a-aα),(aα),(aα)  if pTotal =P1 then kp1=α1+αp1α1+α·p11-α1+α·p1 also X(g)⇌2Y(g) t = 0 b mole teq.  (b-bα) (2bα)  if pTotal =p2 kp2=2α1+α·p221-α1+α·p21  Given :kp1kp2=P14P2=36
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