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Q.

The reaction A→k Products, is zero order while the reaction B→kProducts, is 1st order. For what initial concentration of A the half-lives of the two reactions are equal. Assume rate constants of both reactions are same

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a

2 M

b

ln 2 M

c

2 log 2 M

d

2 ln 2 M

answer is D.

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Detailed Solution

A→kProduct                                  B→kProductzero order                               First order  t1/2=a2K                               t1/2=ln⁡2K⇒a2K=ln⁡2K                                                                  ⇒ a=2ln⁡2
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