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Q.

A reaction occurs spontaneously if

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a

TΔS<ΔH and Both ΔH and ΔS are tue

b

TΔS>ΔH and both ΔH and ΔS are tue

c

TΔS=ΔH and both ΔH and ΔS are +ve

d

TΔS>ΔH and ΔH is +ve and ΔS is −ve

answer is B.

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Detailed Solution

For spontaneous reaction  ∆G should be negativeΔG=ΔH−TΔS=(+ve)−T(+ve)If TΔS>ΔH then ∆G will be negative and reaction will  be spontaneous at high temperature.
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