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Q.

For a reaction, A⇌P, the plots of [A] and [P] with time at temperatures T1 and T2are given below.If T2 > T1, the correct statement(s) is (are)(Assume ΔH0 and ΔS0 are independent of temperature and ratio of lnK at T1 to lnK at T2 is greater than T2T1 . Here H, S, G and K are enthalpy, entropy, Gibbs energy and equilibrium constant, respectively.)

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a

ΔHθ<0,ΔSθ<0

b

ΔGθ<0,ΔHθ>0

c

ΔGθ<0,ΔSθ<0

d

ΔGθ<0,ΔSθ>0

answer is A.

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Detailed Solution

A⇌P given T2>T1ln⁡K1ln⁡K2>T2T1⇒T1ln⁡k1>T2ln⁡k2 ⇒−ΔG10>−ΔG20⇒−ΔH∘+T1ΔS∘>−ΔH∘+T2ΔS∘ ⇒T1ΔS∘>T2ΔS∘⇒ΔS∘<0

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For a reaction, A⇌P, the plots of [A] and [P] with time at temperatures T1 and T2are given below.If T2 > T1, the correct statement(s) is (are)(Assume ΔH0 and ΔS0 are independent of temperature and ratio of lnK at T1 to lnK at T2 is greater than T2T1 . Here H, S, G and K are enthalpy, entropy, Gibbs energy and equilibrium constant, respectively.)