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Q.

The reaction, PCl5  ⇌  PCl3  + Cl2  is started in a 5 litre container by taking one mole of PCl5. If 0.3 mole of PCl5 is there at equilibrium, concentration of PCl3 and KC will respectively be

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a

0.14, 0.326

b

0.12, 0.120

c

0.07, 0.150

d

20, 0.010

answer is A.

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Detailed Solution

PCl5      ⇌           PCl3      +        Cl21                              0                      0       Initial mole1 - 0.75               0.75                 0.75  Conc. at equilibriumTotal mole of PCl3 = 0.7Concentration = 0.14KC = x21-xV= 0.7 × 0.70.3 ×5= 49150=0.326
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The reaction, PCl5  ⇌  PCl3  + Cl2  is started in a 5 litre container by taking one mole of PCl5. If 0.3 mole of PCl5 is there at equilibrium, concentration of PCl3 and KC will respectively be