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Q.

For the reaction , A(aq)+B(aq)⇌C(aq)+D(aq)  an equimolar mixture of A and B are taken initially. If the mole fraction of D at equilibrium is 0.33. What is the value of its equilibrium constant ?

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Detailed Solution

A       +     B     ⇌     C   +   D1−x            1-x               x           x Given x(1−x)+(1−x)+x+x=0.33 x2=0.33 x=0.66 Kc=0.66×0.660.33×0.33=4
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