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Q.

The reaction, X+2Y+Z→N occurs by the following mechanism (i) X+Y⇌M (very rapid equilibrium)(ii) M+Z→O (slow)(iii) O+Y→N (very fast)What is the rate law for this reaction

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a

Rate = k[Z]

b

Rate = k[X][Y]2[Z]

c

Rate = k[N]

d

Rate = k[X][Y][Z]

answer is D.

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Detailed Solution

KC=[M][X][Y]⇒[M]=KC[X][Y]Rate=k'[M][Z]=K'KC[X][Y][Z]                           =K[X][Y][Z]
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The reaction, X+2Y+Z→N occurs by the following mechanism (i) X+Y⇌M (very rapid equilibrium)(ii) M+Z→O (slow)(iii) O+Y→N (very fast)What is the rate law for this reaction