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Q.

In the reactionxHI  +  yHNO3 →  NO  +  I2 + H2O

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a

x = 3, y = 2

b

x = 2, y = 3

c

x = 6, y = 2

d

x = 6, y = 1

answer is C.

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Detailed Solution

xHI  +  yHNO3 →  NO  +  I2 + H2O      Oxidation                                         Reduction       HI→I2                                             HNO3→NO 2HI →I2+2H+                                    HNO3→NO + 2H2O 2HI →I2 +2H++2e-  →(1)             HNO3+3H++3e-→NO + 2H2O→(2)(1) x 3 + (2) x 2 ⇒ 6HI + 2HNO3 →  2NO + 3I2 + 4H2O ⇒x = 6, y = 2
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In the reactionxHI  +  yHNO3 →  NO  +  I2 + H2O