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Q.

For a real gas “X” the Boyle’s temperature point is 240°C.  If the Vander Waals constant “b” is 0.08 dm3 mol-1.  Then the value of constant “a” for “X” is ___?

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a

2.32 atm L2 mol -2

b

513 atmL2mol-2

c

3.37 atm L2 mol-2

d

44.8 atm L2 mol-2

answer is C.

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Detailed Solution

Tb=aRbVander Waals constant “a” for the gas “X” ∴a=Tb×Rb=513×0.0821×0.08=3.37 atmL2 mol-2
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