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Q.

For real gases Vander Waal's equation is written as p+an2V2(V−nb)=nRTwhere 'a' and 'b' are Vander Waal's constants. Two sets of gases are O2,CO2,H2  and He   (II) CH4,O2 and H2The gases given in set-I increasing order of 'b' and gases given in set-ll in decreasing order of ·a', are arranged below. Select the correct order from the following

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a

(I) HeH2>O2

b

(1) O2O2>CH4

c

(I) H2O2>H2

d

(I) H2CH4>H2

answer is C.

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Detailed Solution

Molar mass i. 'a' increases Size of molecule i, 'b' increase b(L/mol)       a bar. .L2/mol2H2→0.02661    CH4→2.283He→0.0237    O2→1.378O2→0.03183    H2→0.2476CO2→0.04267
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