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Q.

A reddish brown sol is obtained by adding small quantity of FeCI3 solution to freshly prepared and well washed Fe(OH)3 ppt. Fixed layer and mobile layer can't be represented as

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a

Fe(OH)3Fe3+:3Cl−

b

Fe(OH)3Fe3+:Cl−

c

FeCl3Fe3+:OH−

d

FeCl3Fe3+:3OH−

answer is B.

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Detailed Solution

Fe(OH)3 sol adsorbs common ion of FeCl3 and Fe(OH)3 from  FeCl3, i.e. Fe3+ and positively charged sol is the fixed part of the electrical double layer. Thus, CI- (to balance charge of Fes3+) ions are on the mobile part of the electrical double layer.Fe(OH)3FixedFe3+:3Cl−Mobile
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