For the redox reaction,xFe2+ + yCr2O72- + zH+ → Fe3+ + Cr3+ + H2Ox, y and z are
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a
x = 3, y = 1, z = 14
b
x = 6, y = 1, z = 7
c
x = 6, y = 2, z = 14
d
x = 6, y = 1, z = 14
answer is D.
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Detailed Solution
To balance a redox reaction, balance effected atoms(I) Fe2+ → Fe3+ (Fe-balanced)(II) Take oxidation number of two Cr-atomCr+62O72- → 2Cr+3 (Cr-balanced)Take total (oxidation number) of each atom (oxidized, reduced) cross-multiplied by change in oxidation number and addI×6+II×1 6Fe2++Cr2O72- → 6Fe+3+2Cr+3Balance O, by H2O .... + 7H2OBalance H, by H+..... + 14H+The balanced equation is 6Fe+2+Cr2O7-2+14H+→6Fe+3+2Cr+3+7H2OThus, x = 6 y = 1 z = 14