Q.
Reduction potential of chlorine electrode in contact with 0.01 M HCl solution is EPt,Cl2/Cl-o=+1.36 V
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a
1.24 V
b
1.3 V
c
1.42 V
d
1.48 V
answer is D.
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Detailed Solution
For non-metal electrodesERP=ERPo−0.0591nlogX−nCl2+2e−→2Cl−ERP=+1.36−0.05912log0.012ERP=1.36−0.0591log 10−2ERP=1.48 V
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