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Q.

Reduction potential of chlorine electrode in contact with 0.01 M HCl solution is EPt,Cl2/Cl-o=+1.36 V

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a

1.24 V

b

1.3 V

c

1.42 V

d

1.48 V

answer is D.

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Detailed Solution

For non-metal electrodesERP=ERPo−0.0591nlogX−nCl2+2e−→2Cl−ERP=+1.36−0.05912log0.012ERP=1.36−0.0591log 10−2ERP=1.48 V
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Reduction potential of chlorine electrode in contact with 0.01 M HCl solution is EPt,Cl2/Cl-o=+1.36 V